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The Pauli exclusion principle is the quantum mechanical principle that states that two identical fermions (particles with half-integer spin) cannot occupy the same quantum state simultaneously. In the case of electrons, it can be stated as follows: it is impossible for two electrons of a poly-electron atom to have the same values of the four quantum numbers: ''n'', the principal quantum number, ' , the angular momentum quantum number, ''m'', the magnetic quantum number, and ''ms'', the spin quantum number. For two electrons residing in the same orbital, ''n'', ', and ''m'' are the same, so ''ms'', the spin, must be different, and thus the electrons have opposite half-integer spins, 1/2 and -1/2. This principle was formulated by Austrian physicist Wolfgang Pauli in 1925. A more rigorous statement is that the total wave function for two identical fermions is antisymmetric with respect to exchange of the particles. This means that the wave function changes its sign if the space ''and'' spin co-ordinates of any two particles are interchanged. Particles with an integer spin, or bosons, are not subject to the Pauli exclusion principle: any number of identical bosons can occupy the same quantum state, as with, for instance, photons produced by a laser and Bose–Einstein condensate. ==Overview== The Pauli exclusion principle governs the behavior of all fermions (particles with "half-integer spin"), while bosons (particles with "integer spin") are not subject to it. Fermions include elementary particles such as quarks (the constituent particles of protons and neutrons), electrons and neutrinos. In addition, protons and neutrons (subatomic particles composed from three quarks) and some atoms are fermions, and are therefore subject to the Pauli exclusion principle as well. Atoms can have different overall "spin", which determines whether they are fermions or bosons — for example helium-3 has spin 1/2 and is therefore a fermion, in contrast to helium-4 which has spin 0 and is a boson. As such, the Pauli exclusion principle underpins many properties of everyday matter, from its large-scale stability, to the chemical behavior of atoms. "Half-integer spin" means that the intrinsic angular momentum value of fermions is (reduced Planck's constant) times a half-integer (1/2, 3/2, 5/2, etc.). In the theory of quantum mechanics fermions are described by antisymmetric states. In contrast, particles with integer spin (called bosons) have symmetric wave functions; unlike fermions they may share the same quantum states. Bosons include the photon, the Cooper pairs which are responsible for superconductivity, and the W and Z bosons. (Fermions take their name from the Fermi–Dirac statistical distribution that they obey, and bosons from their Bose–Einstein distribution). 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Pauli exclusion principle」の詳細全文を読む スポンサード リンク
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